Well, you do know that the Vista also mirrors the original files from the Program Files, so you can't actually change them?...
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I would suggest that you move the game to a none-Program Files directory to get rid of the Vista's program files mirroring, and then edit the baldur.ini to reflect the changes under the [Alias] header, and then just start the game from the BGMain.exe...
What the hell, this actually worked! Thanks!